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Pure Appl. Chem., 2008, Vol. 80, No. 5, pp. 1179-1185

http://dx.doi.org/10.1351/pac200880051179

Cationic palladium-catalyzed hydrosilylative cross-coupling of alkynes with alkenes forming 4-silylated-1-butene frameworks

Takamitsu Shimamoto, Motoharu Chimori, Hiroaki Sogawa, Yuki Harada, Masaharu Aoki and Keiji Yamamoto

Department of Materials Science and Environmental Engineering, Tokyo University of Science, Yamaguchi, 1-1-1 Daigaku-Dori, Sanyo-Onoda, Yamaguchi 756-0884, Japan

References

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  • 7. In the chemical formula, the designations a or b and 1 or 2 refer to the carbopalladation that occurs at a or b position of the 1-alkyne employed, and C-Si bond occurring at terminal or internal carbon of the 1-alkene counterpart, respectively.
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  • 9. Throughout this section, all chemical names for the products of hydrosilylative cross-coupling of alkynes with alkenes are given on the basis of common 4-organosilyl-1-butene frameworks, R1CH=CR2-CHR3-CHR4-SiX3 (X = Cl or OEt), and not consonant with those by CAS (9CI).