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Pure Appl. Chem., 2009, Vol. 81, No. 7, pp. 1187-1195

http://dx.doi.org/10.1351/PAC-CON-08-07-19

Published online 2009-06-29

Structural tuning and self-association of (arylimido)vanadium(V) compounds

Toshiyuki Moriuchi and Toshikazu Hirao*

Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan

Abstract: Structural tuning and self-association of (arylimido)vanadium(V) compounds are demonstrated to be controlled through π-conjugation by the para-substituents of the aryl moieties.