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Pure Appl. Chem., 2006, Vol. 78, No. 8, pp. 1571-1586

http://dx.doi.org/10.1351/pac200678081571

When spectroscopy fails: The measurement of ion pairing

Glenn Hefter

Chemistry Department, Murdoch University, Murdoch, WA 6150, Australia

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  • Rubinson Kenneth A.: Small-Angle Neutron Scattering of Aqueous SrI2 Suggests a Mechanism for Ion Transport in Molecular Water. J Solution Chem 2014, 43, 453. <http://dx.doi.org/10.1007/s10953-014-0148-5>
  • Bešter-Rogač Marija, Stoppa Alexander, Buchner Richard: Ion Association of Imidazolium Ionic Liquids in Acetonitrile. J. Phys. Chem. B 2014, 118, 1426. <http://dx.doi.org/10.1021/jp412344a>
  • Di Tommaso Devis, Ruiz-Agudo Encarnación, de Leeuw Nora H., Putnis Andrew, Putnis Christine V.: Modelling the effects of salt solutions on the hydration of calcium ions. Phys. Chem. Chem. Phys. 2014, 16, 7772. <http://dx.doi.org/10.1039/c3cp54923b>
  • Laborda Eduardo, Batchelor-McAuley Christopher, Suwatchara Danu, Henstridge Martin C., Compton Richard G.: On the adiabaticity of electrode processes: Effect of the supporting electrolyte cation on the kinetics of electroreduction of 3-nitrophenolate. Journal of Electroanalytical Chemistry 2013, 694, 30. <http://dx.doi.org/10.1016/j.jelechem.2013.02.010>
  • Fleshman Allison M., Petrowsky Matt, Frech Roger: Concentration Dependence of Molal Conductivity and Dielectric Constant of 1-Alcohol Electrolytes Using the Compensated Arrhenius Formalism. J. Phys. Chem. B 2013, 117, 5330. <http://dx.doi.org/10.1021/jp312243d>
  • Fuchs Anna, Buchner Richard, Hefter Glenn: Solvation and Association of 3:1 Electrolytes in N,N-Dimethylformamide. J. Phys. Chem. B 2013, 117, 14468. <http://dx.doi.org/10.1021/jp4089436>
  • Mishustin A. I.: Temperature dependence of ion association constants in nonaqueous solutions of metal perchlorates. Russ. J. Inorg. Chem. 2013, 58, 684. <http://dx.doi.org/10.1134/S0036023613060181>
  • Powell Kipton J., Brown Paul L., Byrne Robert H., Gajda Tamas, Hefter Glenn, Leuz Ann-Kathrin, Sjöberg Staffan, Wanner Hans: Chemical speciation of environmentally significant metals with inorganic ligands. Part 5: The Zn2+ + OH–, Cl–, CO32–, SO42–, and PO43– systems (IUPAC Technical Report). Pure Appl. Chem. 2013, 1. <http://dx.doi.org/10.1351/PAC-REP-13-06-03>
  • Phillips Hazel I. A., Chernikov Aleksey V., Fletcher Nicholas C., Ashcroft Alison E., Ault James R., Filby Maria H., Wilson Andrew J.: The Use of Electrospray Mass Spectrometry to Determine Speciation in a Dynamic Combinatorial Library for Anion Recognition. Chem. Eur. J. 2012, 18, 13733. <http://dx.doi.org/10.1002/chem.201201302>
  • Gafurov M. M., Rabadanov K. Sh., Ataev M. B., Aliev A. R., Ahmedov I. R., Kakagasanov M. G., Kraminin S. P.: Vibrational spectra of an LiNO3–(CH3)2SO2 system. J Appl Spectrosc 2012, 79, 184. <http://dx.doi.org/10.1007/s10812-012-9581-7>
  • Cauët Emilie, Bogatko Stuart A., Bylaska Eric J., Weare John H.: Ion Association in AlCl3 Aqueous Solutions from Constrained First-Principles Molecular Dynamics. Inorg. Chem. 2012, 51, 10856. <http://dx.doi.org/10.1021/ic301346k>
  • Schröder Detlef: Ion clustering in electrospray mass spectrometry of brine and other electrolyte solutions. PCCP 2012, 14, 6382. <http://dx.doi.org/10.1039/c2cp40586e>
  • Mishustin A. I.: Stability constants of tervalent actinide and lanthanide sulfate complexes in aqueous solutions. Russ J Inorg Chem 2012, 57, 712. <http://dx.doi.org/10.1134/S0036023612050166>
  • Noblitt Scott D., Speights Rachel M., Henry Charles S.: Protonated diamines as anion-binding agents and their utility in capillary electrophoresis separations. Eletrophoresis 2011, 32, 2986. <http://dx.doi.org/10.1002/elps.201100252>
  • Révész Ágnes, Schröder Detlef, Svec Jan, Wimmerová Michaela, Sindelar Vladimir: Anion Binding by Bambus[6]uril Probed in the Gas Phase and in Solution. J Phys Chem A 2011, 115, 11378. <http://dx.doi.org/10.1021/jp205218k>
  • Bešter-Rogač Marija, Stoppa Alexander, Hunger Johannes, Hefter Glenn, Buchner Richard: Association of ionic liquids in solution: a combined dielectric and conductivity study of [bmim][Cl] in water and in acetonitrile. PCCP 2011, 13, 17588. <http://dx.doi.org/10.1039/c1cp21371g>
  • Szymański Krzysztof, Petrache Horia I.: Composite polarizability and the construction of an invariant function of refraction and mass density for solutions. J Chem Phys 2011, 134, 144701. <http://dx.doi.org/10.1063/1.3576132>
  • Hochstrasser Robin M., Kuroda Daniel G.: Two-dimensional infrared spectral signature and hydration of the oxalate dianion. Journal Chemical Physics 2011, 135, 204502. <http://dx.doi.org/10.1063/1.3658461>
  • Powell Kipton J., Brown Paul L., Byrne Robert H., Gajda Tamas, Hefter Glenn, Leuz Ann-Kathrin, Sjöberg Staffan, Wanner Hans: Chemical speciation of environmentally significant metals with inorganic ligands. Part 4: The Cd2+ + OH–, Cl–, CO32–, SO42–, and PO43– systems (IUPAC Technical Report). Pure and App Chemis 2011, 1. <http://dx.doi.org/10.1351/PAC-REP-10-08-09>
  • Nakashima T., Waki H., Toh M.: A Theoretical Interpretation for the Difference Between Stability Constants of the Same Metal Complex Determined by Different Analytical Methods. J Solution Chem 2010, 39, 51. <http://dx.doi.org/10.1007/s10953-009-9482-4>
  • Moreno Aitor, Pregosin Paul S., Veiros Luis F., Albinati Alberto, Rizzato Silvia: Ion Pairing and Salt Structure in Organic Salts through Diffusion, Overhauser, DFT and X-ray Methods. Chem Eur J 2009, 15, 6848. <http://dx.doi.org/10.1002/chem.200900021>
  • Buchner Richard, Hefter Glenn: Interactions and dynamics in electrolyte solutions by dielectric spectroscopy. Phys Chem Chem Phys 2009, 11, 8984. <http://dx.doi.org/10.1039/b906555p>
  • Szilágyi István, Königsberger Erich, May Peter M.: Spectroscopic characterisation of weak interactions in acidic titanyl sulfate–iron(ii) sulfate solutions. Dalton Trans 2009, 7717. <http://dx.doi.org/10.1039/b906803a>
  • Migdisov Art. A., Williams-Jones A.E.: A spectrophotometric study of Nd(III), Sm(III) and Er(III) complexation in sulfate-bearing solutions at elevated temperatures. Geochimica et Cosmochimica Acta 2008, 72, 5291. <http://dx.doi.org/10.1016/j.gca.2008.08.002>
  • Owrutsky Jeffrey C., Pomfret Michael B., Barton David J., Kidwell David A.: Fourier transform infrared spectroscopy of azide and cyanate ion pairs in AOT reverse micelles. J Chem Phys 2008, 129, 024513. <http://dx.doi.org/10.1063/1.2952522>
  • Schrödle Simon, Rudolph Wolfram W., Hefter Glenn, Buchner Richard: Ion association and hydration in 3:2 electrolyte solutions by dielectric spectroscopy: Aluminum sulfate. Geochimica et Cosmochimica Acta 2007, 71, 5287. <http://dx.doi.org/10.1016/j.gca.2007.08.026>
  • Akilan Chandrika, Rohman Nashiour, Hefter Glenn, Buchner Richard: Temperature Effects on Ion Association and Hydration in MgSO4 by Dielectric Spectroscopy. Chem Eur J of Chem Phys 2006, 7, 2319. <http://dx.doi.org/10.1002/cphc.200600342>