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Pure Appl. Chem., 2010, Vol. 82, No. 9, pp. 1845-1853

http://dx.doi.org/10.1351/PAC-CON-09-09-40

Published online 2010-05-30

Enantioselective reactions catalyzed by chiral pyridine 2,6-bis(5',5'-diphenyloxazoline)-metal complexes

Pradeep K. Singh1 and Vinod K. Singh1,2*

1 Department of Chemistry, Indian Institute of Technology, Kanpur 208 016, India
2 Indian Institute of Science Education and Research, ITI Campus (Gas Rahat) Building, Govindpura, Bhopal 460 023, India

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  • Schulz Marvin, Christoffers Jens: Synthesis of Functionalized Pyridine-2,6-bis(imidazolines) by Ring Transformation of 4-(Aminomethyl)oxazoline Derivatives. Eur. J. Org. Chem. 2013, 2013, 7624. <http://dx.doi.org/10.1002/ejoc.201301204>
  • Samadi Saadi, Nazari Saber, Arvinnezhad Hamid, Jadidi Khosrow, Notash Behrouz: A significant improvement in enantioselectivity, yield, and reactivity for the copper-bi-o-tolyl bisoxazoline-catalyzed asymmetric allylic oxidation of cyclic olefins using recoverable SBA-15 mesoporous silica material. Tetrahedron 2013, 69, 6679. <http://dx.doi.org/10.1016/j.tet.2013.05.119>
  • Samadi Saadi, Jadidi Khosrow, Notash Behrouz: Chiral bisoxazoline ligands with a biphenyl backbone: development and application in catalytic asymmetric allylic oxidation of cycloolefins. Tetrahedron: Asymmetry 2013, 24, 269. <http://dx.doi.org/10.1016/j.tetasy.2013.01.013>
  • Zou Jin, Berg David J., Oliver Allen, Twamley Brendan: Unusual Redox Chemistry of Ytterbium Carbazole–Bis(oxazoline) Compounds: Oxidative Coupling of Primary Phosphines by an Ytterbium Carbazole–Bis(oxazoline) Dialkyl. Organometallics 2013, 32, 6532. <http://dx.doi.org/10.1021/om400861d>
  • Ray Sumit K., Rout Subhrajit, Singh Vinod K.: Enantioselective synthesis of 3,4-dihydropyran derivatives via a Michael addition reaction catalysed by chiral pybox–diph–Zn(ii) complex. Org. Biomol. Chem. 2013, 11, 2412. <http://dx.doi.org/10.1039/c3ob40246k>
  • Rout Subhrajit, Ray Sumit K., Singh Vinod K.: Enantioselective Mukaiyama–Michael with 2-enoyl pyridine N-oxides catalyzed by PYBOX-DIPH-Zn(ii)-complexes at ambient temperature. Org. Biomol. Chem. 2013, 11, 4537. <http://dx.doi.org/10.1039/c3ob40445e>
  • Bisai Alakesh, Singh Vinod K.: Enantioselective one-pot three-component synthesis of propargylamines catalyzed by copper(I)–pyridine bis-(oxazoline) complexes. Tetrahedron 2012, 68, 3480. <http://dx.doi.org/10.1016/j.tet.2011.05.114>
  • Ray Sumit K., Singh Pradeep K., Molleti Nagaraju, Singh Vinod K.: Enantioselective Synthesis of Coumarin Derivatives by PYBOX-DIPH-Zn(II) Complex Catalyzed Michael Reaction. J. Org. Chem. 2012, 77, 8802. <http://dx.doi.org/10.1021/jo301513x>
  • Matz Dallas L., Pemberton Jeanne E.: Reaction Chemistry of Solid-State Pyridine Thin Films with Vapor Deposited Ag, Mg, and Al. J Phys Chem C 2012, 120517163014000. <http://dx.doi.org/10.1021/jp300795c>
  • Singh Pradeep K., Singh Vinod K.: Chiral 2,6-bis(5',5'-diphenyloxazoline)pyridine as an efficient ligand for asymmetric catalysis. Pure Appl. Chem. 2012, 1. <http://dx.doi.org/10.1351/PAC-CON-11-10-16>
  • Singh Pradeep K., Singh Vinod K.: ChemInform Abstract: Enantioselective Reactions Catalyzed by Chiral Pyridine 2,6-Bis(5′,5′-diphenyloxazoline)-metal Complexes. ChemInform 2011, 42, no. <http://dx.doi.org/10.1002/chin.201110238>
  • Ray Sumit K., Singh Pradeep K., Singh Vinod K.: Enantioselective Michael Addition of Malonates to 2-Enoylpyridine N-Oxides Catalyzed by Chiral Bisoxazoline–Zn(II) Complex. Org Lett 2011, 13, 5812. <http://dx.doi.org/10.1021/ol202405v>
  • Zou Jin, Berg David J., Stuart David, McDonald Robert, Twamley Brendan: Carbazole-bis(oxazolines) as Monoanionic, Tridentate Chelates in Lanthanide Chemistry: Synthesis and Structural Studies of Thermally Robust and Kinetically Stable Dialkyl and Dichloride Complexes. Organometallics 2011, 30, 4958. <http://dx.doi.org/10.1021/om200588y>