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Pure Appl. Chem., 2012, Vol. 84, No. 3, pp. 439-459

http://dx.doi.org/10.1351/PAC-CON-11-07-11

Published online 2012-01-17

Novel general halogen-free methodology for the synthesis of organophosphorus compounds*

Nina K. Gusarova, Svetlana N. Arbuzova and Boris A. Trofimov*

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation

Abstract: The use of novel general halogen-free methodology for the synthesis of phosphines, phosphine chalcogenides, and phosphinic acids from elemental phosphorus and alkenes and alkynes in the superbase suspensions is described.
*Pure Appl. Chem. 84, 411–860 (2012). A collection of invited papers for the IUPAC project 2008-016-1-300 “Chlorine-free Synthesis for Green Chemistry”.