V. V. Boldyrev
Blackwell Science, 1996 [ISBN 0865426872]
In the best tradition of the IUPAC Chemistry
for the 21st Century series, this latest title presents a series of
state-of-the-art reviews on the reactivity of solids. Each of the articles,
written by leading experts, provides a wide overview of progress in
the field, evaluates the state of research at present and examines the
prospects for the future. The book covers the problems related to the
hierarchy of defects in solids, the kinetics of chemical reactions in
solids, and the reactions in solid matrices. It also considers in some
detail various types of heterogeneous reactions, homogeneous reactions
and chemical reactions in organic solids. Special chapters are devoted
to the application of solid state reactions in inorganic synthesis and
the manufacture of new materials.
Contents
Preface - Reactivity of solids: past, present
and future; Hierarch of defects in crystals and reactivities of solids;
The reactivity of solids in thermal decomposition (crystolysis) reactions;
Problems
of reactivity in the dissolution of inorganic solids; Some data on surface
properties and reactivity of metal oxides; Processes at interfaces during
solid state reactions; Modern tendencies in heterogeneous kinetics of
solid state decomposition reactions;
Homogeneous solid state reactions; Kinetics of the simplest radical
reactions in solids; Reactivity of organic solids - past, present and
future; Chemical strategies for the synthesis of metal oxides; Low temperature
materials syntheses; Reactivity of
solids and new technologies.
103 illustrations
304 pages
